Issue 33, 2012

Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

Abstract

New quadruply bonded dimolybdenum complexes of the terphenyl ligand ArXyl2 (ArXyl2 = C6H3-2,6-(C6H3-2,6-Me2)2) have been prepared and structurally characterized. The steric hindrance exerted by the ArXyl2 groups causes the Mo atoms to feature unsaturated four-coordinate structures and a formal fourteen-electron count.

Graphical abstract: Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

Supplementary files

Article information

Article type
Communication
Submitted
17 Jan 2012
Accepted
25 Feb 2012
First published
28 Feb 2012

Chem. Commun., 2012,48, 3954-3956

Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

M. Carrasco, M. Faust, R. Peloso, A. Rodríguez, J. López-Serrano, E. Álvarez, C. Maya, P. P. Power and E. Carmona, Chem. Commun., 2012, 48, 3954 DOI: 10.1039/C2CC30394A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements