Issue 48, 2012

Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

Abstract

Exploiting a non-linear response for chiral discrimination, an intelligent system capable of chirality amplification was designed and constructed as poly(phenyleneethynylene) having chiral pseudo-18-crown-6. Both sensitivity and selectivity were amplified from those limited by the law of mass action.

Graphical abstract: Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

  • This article is part of the themed collection: Chirality

Supplementary files

Article information

Article type
Communication
Submitted
18 Jan 2012
Accepted
25 Apr 2012
First published
26 Apr 2012

Chem. Commun., 2012,48, 6052-6054

Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

K. Hirose, S. Miura, Y. Senda and Y. Tobe, Chem. Commun., 2012, 48, 6052 DOI: 10.1039/C2CC30417A

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