Issue 32, 2012
From the journal:

Chemical Communications

Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks†

Juan Diwua  and  Thomas E. Albrecht-Schmitt*a  

* Corresponding authors

a Department of Chemistry and Biochemistry and Department of Civil Engineering and Geological Sciences, 156 Fitzpatrick Hall, University of Notre Dame, Notre Dame, Indiana 46556, USA
E-mail: talbrec1@nd.edu

Abstract

Two chiral, porous uranium methylenediphosphonates, [C2H10N2]{UO2[CH2(PO3)2]}·H2O (UC1P2N-1) and [N(C2H5)4]K{(UO2)3[CH2(PO3)2]2(H2O)2}·1.5H2O (KUC1P2-1), have been synthesized without chiral starting materials. Both compounds display channels ∼1 × 1 nm that are large enough for these materials to conduct ion-exchange with coordination complexes such as [Co(en)3]3+.

Graphical abstract: Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks

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Article information

DOI
https://doi.org/10.1039/C2CC30519D
Article type
Communication
Submitted
23 Jan 2012
Accepted
22 Feb 2012
First published
23 Feb 2012

Chem. Commun., 2012,48, 3827-3829

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Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks

J. Diwu and T. E. Albrecht-Schmitt, Chem. Commun., 2012, 48, 3827 DOI: 10.1039/C2CC30519D

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