Issue 35, 2012
From the journal:

Chemical Communications

Hangman effect on hydrogen peroxide dismutation by Fe(iii) corroles†

Daniel J. Graham,a   Dilek K. Dogutan,a   Matthias Schwalbea  and  Daniel G. Nocera*a  

* Corresponding authors

a Department of Chemistry, 6-335, Massachusetts Institute of Technology, Cambridge, USA
E-mail: nocera@mit.edu

Abstract

Hangman Fe(III) corroles catalyse H2O2 disproportionation at a faster rate and display a more pronounced hangman effect than their one electron oxidized analogues owing to their ability to bypass high energy intermediates by redox-leveling derived from the use of the corrole as a non-innocent ligand.

Graphical abstract: Hangman effect on hydrogen peroxide dismutation by Fe(iii) corroles

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Article information

DOI
https://doi.org/10.1039/C2CC30580A
Article type
Communication
Submitted
26 Jan 2012
Accepted
07 Mar 2012
First published
08 Mar 2012

Chem. Commun., 2012,48, 4175-4177

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Hangman effect on hydrogen peroxide dismutation by Fe(III) corroles

D. J. Graham, D. K. Dogutan, M. Schwalbe and D. G. Nocera, Chem. Commun., 2012, 48, 4175 DOI: 10.1039/C2CC30580A

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