Neutral copper–phosphido-borane complexes: synthesis, characterization, and use as precatalysts in Csp–P bond formation

Ibrahim Abdellah; Elise Bernoud; Jean-François Lohier; Carole Alayrac; Loïc Toupet; Christine Lepetit; Annie-Claude Gaumont

doi:10.1039/C2CC30723E

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Neutral copper–phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C_sp–P bond formation†

Ibrahim Abdellah,^a Elise Bernoud,^a Jean-François Lohier,^a Carole Alayrac,^a Loïc Toupet,^b Christine Lepetit^cd and Annie-Claude Gaumont*^a

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* Corresponding authors

^a Laboratoire de Chimie Moléculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Université de Caen, 6 boulevard du Maréchal Juin, France
E-mail: annie-claude.gaumont@ensicaen.fr
Fax: +33 2 31 45 28 77
Tel: +33 2 31 45 28 73

^b Institut de Physique de Rennes, UMR CNRS 6251, Université de Rennes 1, 263 avenue du Général Leclerc, France

^c CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, France
E-mail: christine.lepetit@lcc-toulouse.fr
Fax: +33 5 61 55 30 03
Tel: +33 5 61 33 31 36

^d Université de Toulouse, UPS, INPT, LCC, France

Abstract

Copper–phosphido-borane complexes were synthesized and isolated for the first time. Their structures were experimentally and computationally investigated. They were shown to display catalytic activity in C_sp–P bond formation.

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Article information

DOI: https://doi.org/10.1039/C2CC30723E
Article type: Communication
Submitted: 01 Feb 2012
Accepted: 24 Feb 2012
First published: 20 Mar 2012

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Chem. Commun., 2012,48, 4088-4090

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Neutral copper–phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C_sp–P bond formation

I. Abdellah, E. Bernoud, J. Lohier, C. Alayrac, L. Toupet, C. Lepetit and A. Gaumont, Chem. Commun., 2012, 48, 4088 DOI: 10.1039/C2CC30723E

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