Issue 40, 2012
From the journal:

Chemical Communications

Monomeric Sn(ii) and Ge(ii) hydrides supported by a tridentate pincer-based ligand†‡

Shabana Khan,a   Prinson P. Samuel,a   Reent Michel,a   Johannes M. Dieterich,b   Ricardo A. Mata,*b   Jean-Philippe Demers,c   Adam Lange,c   Herbert W. Roesky*a  and  Dietmar Stalke*a  

* Corresponding authors

a Institut für Anorganische Chemie, Georg-August-Universität, Tammannstrasse 4, 37077 Göttingen, Germany
E-mail: hroesky@gwdg.de, dstalke@chemie.uni-goettingen.de

b Institut für Physikalische Chemie, Georg-August-Universität, Tammannstrasse 6, 37077 Göttingen, Germany
E-mail: rmata@gwdg.de

c Solid-State NMR, Max-Planck-Institut für Biophysikalische Chemie, Am Faßberg 11, 37077 Göttingen, Germany

Abstract

Herein we report the syntheses of terminal Sn(II) (3) and Ge(II) (4) hydrides from the corresponding chloride precursors [{2,6-iPr2C6H3NCMe}2C6H3MCl] (M = Sn (1), Ge (2)) using [K{B(sec-Bu)3}H] as a hydrogenating agent. Combination of steric shielding and intramolecular N → M interactions resulted in the protection of M(II)–H bonds.

Graphical abstract: Monomeric Sn(ii) and Ge(ii) hydrides supported by a tridentate pincer-based ligand

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Article information

DOI
https://doi.org/10.1039/C2CC31214J
Article type
Communication
Submitted
17 Feb 2012
Accepted
12 Mar 2012
First published
14 Mar 2012

Chem. Commun., 2012,48, 4890-4892

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Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand

S. Khan, P. P. Samuel, R. Michel, J. M. Dieterich, R. A. Mata, J. Demers, A. Lange, H. W. Roesky and D. Stalke, Chem. Commun., 2012, 48, 4890 DOI: 10.1039/C2CC31214J

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