Issue 38, 2012

Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

Abstract

A straightforward procedure based on the formation of intramolecular hydrogen bonds to impart selectivity in the preparation of multi-functionalized porphyrins has been developed. To illustrate the concept, the synthesis of a biomimetic artificial photosynthetic model able to undergo electron and proton transfer reactions upon irradiation is reported.

Graphical abstract: Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

Supplementary files

Article information

Article type
Communication
Submitted
17 Feb 2012
Accepted
02 Mar 2012
First published
04 Apr 2012

Chem. Commun., 2012,48, 4558-4560

Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

J. D. Megiatto, D. Patterson, B. D. Sherman, T. A. Moore, D. Gust and A. L. Moore, Chem. Commun., 2012, 48, 4558 DOI: 10.1039/C2CC31228J

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