Unusual microporous polycatenane-like metal–organic frameworks for the luminescent sensing of Ln3+ cations and rapid adsorption of iodine

Lei Chen; Ke Tan; Ya-Qian Lan; Shun-Li Li; Kui-Zhan Shao; Zhong-Min Su

doi:10.1039/C2CC31257C

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Unusual microporous polycatenane-like metal–organic frameworks for the luminescent sensing of Ln³⁺cations and rapid adsorption of iodine†

Lei Chen,^a Ke Tan,^b Ya-Qian Lan,^a Shun-Li Li,*^a Kui-Zhan Shao^a and Zhong-Min Su*^a

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* Corresponding authors

^a Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, People's Republic of China
E-mail: lisl132@nenu.edu.cn, zmsu@nenu.edu.cn

^b Biological Scientific and Technical College, Changchun University, Changchun, People's Republic of China

Abstract

Two isostructural 2D → 2D parallel → 3D inclined interpenetrating polycatenane-like metal–organic frameworks were successfully constructed based on length-adjusted tricarboxylate ligands. With the merit of being microporous, IFMC-10 can serve as host for encapsulating lanthanide cations and I₂ to exhibit luminescent sensing and rapid adsorption of iodine.

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Article information

DOI: https://doi.org/10.1039/C2CC31257C
Article type: Communication
Submitted: 20 Feb 2012
Accepted: 17 Apr 2012
First published: 18 Apr 2012

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Chem. Commun., 2012,48, 5919-5921

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Unusual microporous polycatenane-like metal–organic frameworks for the luminescent sensing of Ln³⁺ cations and rapid adsorption of iodine

L. Chen, K. Tan, Y. Lan, S. Li, K. Shao and Z. Su, Chem. Commun., 2012, 48, 5919 DOI: 10.1039/C2CC31257C

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Chemical Communications