Issue 54, 2012
From the journal:

Chemical Communications

A non-fused mono-meso-free pentaphyrin and its rhodium(i) complex†

Tomoki Yoneda,a   Hirotaka Mori,a   Byung Sun Lee,b   Min-Chul Yoon,b   Dongho Kim*b  and  Atsuhiro Osuka*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Sakyo-ku, Japan
E-mail: osuka@kuchem-u.ac.jp
Fax: +81-75-753-3970

b Spectroscopy Laboratory for Functional π-electronic Systems and Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr
Fax: +82-2-364-7050

Abstract

5,10,15,20-Tetrakis(pentafluorophenyl) [22]pentaphyrin(1.1.1.1.1) 7 was synthesised and its bis-rhodium(I) complex 12 has been revealed to be a non-fused, yet planar pentaphyrin with an inverted pyrrole. Both 7 and 12 are aromatic, showing sharp Soret-like bands and diatropic ring currents.

Graphical abstract: A non-fused mono-meso-free pentaphyrin and its rhodium(i) complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC32054A
Article type
Communication
Submitted
21 Mar 2012
Accepted
10 May 2012
First published
18 May 2012

Chem. Commun., 2012,48, 6785-6787

Permissions

Request permissions

A non-fused mono-meso-free pentaphyrin and its rhodium(I) complex

T. Yoneda, H. Mori, B. Sun Lee, M. Yoon, D. Kim and A. Osuka, Chem. Commun., 2012, 48, 6785 DOI: 10.1039/C2CC32054A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements