Issue 54, 2012
From the journal:

Chemical Communications

Formation of a surface covalent organic framework based on polyester condensation†

Antonela C. Marele,a   Rubén Mas-Ballesté,b   Luigi Terracciano,a   Jonathan Rodríguez-Fernández,a   Isadora Berlanga,b   Simone S. Alexandre,c   Roberto Otero,ad   José M. Gallego,de   Félix Zamora*b  and  José M. Gómez-Rodríguez*a  

* Corresponding authors

a Dpto. de Física de la Materia Condensada, Universidad Autónoma de Madrid, 28049 Madrid, Spain
E-mail: josem.gomez@uam.es

b Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain
E-mail: felix.zamora@uam.es

c Departamento de Física, Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil

d Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanociencia), 28049 Madrid, Cantoblanco, Spain

e Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC, 28049 Madrid, Cantoblanco, Spain

Abstract

The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.

Graphical abstract: Formation of a surface covalent organic framework based on polyester condensation

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Article information

DOI
https://doi.org/10.1039/C2CC32270F
Article type
Communication
Submitted
29 Mar 2012
Accepted
14 Apr 2012
First published
16 Apr 2012

Chem. Commun., 2012,48, 6779-6781

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Formation of a surface covalent organic framework based on polyester condensation

A. C. Marele, R. Mas-Ballesté, L. Terracciano, J. Rodríguez-Fernández, I. Berlanga, S. S. Alexandre, R. Otero, J. M. Gallego, F. Zamora and J. M. Gómez-Rodríguez, Chem. Commun., 2012, 48, 6779 DOI: 10.1039/C2CC32270F

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