Hybrid porous tin(IV) phosphonate: an efficient catalyst for adipic acid synthesis and a very good adsorbent for CO2 uptake

Arghya Dutta; Malay Pramanik; Astam K. Patra; Mahasweta Nandi; Hiroshi Uyama; Asim Bhaumik

doi:10.1039/C2CC32298F

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Hybrid porous tin(iv) phosphonate: an efficient catalyst for adipic acid synthesis and a very good adsorbent for CO₂ uptake†

Arghya Dutta,^a Malay Pramanik,^a Astam K. Patra,^a Mahasweta Nandi,^b Hiroshi Uyama^b and Asim Bhaumik*^a

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* Corresponding authors

^a Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India
E-mail: msab@iacs.res.in
Fax: +91-33-2473-2805

^b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

A new porous organic–inorganic hybrid tin phosphonate material has been synthesized hydrothermally, which shows a Brunauer–Emmett–Teller surface area of 723 m² g⁻¹ and it adsorbs 4.8 mmol g⁻¹ CO₂ at 273 K and 5 bar pressure. The material also shows remarkable catalytic activity in one-pot liquid phase oxidation of cyclohexanone to adipic acid under eco-friendly conditions.

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Article information

DOI: https://doi.org/10.1039/C2CC32298F
Article type: Communication
Submitted: 30 Mar 2012
Accepted: 09 May 2012
First published: 10 May 2012

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Chem. Commun., 2012,48, 6738-6740

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Hybrid porous tin(IV) phosphonate: an efficient catalyst for adipic acid synthesis and a very good adsorbent for CO₂ uptake

A. Dutta, M. Pramanik, A. K. Patra, M. Nandi, H. Uyama and A. Bhaumik, Chem. Commun., 2012, 48, 6738 DOI: 10.1039/C2CC32298F

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