Issue 55, 2012
From the journal:

Chemical Communications

Enhancement of Brønsted acidity in zeolitic catalysts due to an intermolecular solvent effect in confined micropores†

Anmin Zheng,a   Bing Han,a   Bojie Li,a   Shang-Bin Liu*bc  and  Feng Deng*a  

* Corresponding authors

a State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan 430071, China
E-mail: dengf@wipm.ac.cn

b Institute of Atomic and Molecular Sciences, Academia Sinica, P. O. Box 23-166, Taipei 10617, Taiwan

c Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan
E-mail: sbliu@sinica.edu.tw

Abstract

Solid-state NMR and DFT calculation studies certified the presence of an intermolecular solvent effect for molecules confined in microporous zeolite, leading to a notable increase in Brønsted acidity of the solid acid catalyst.

Graphical abstract: Enhancement of Brønsted acidity in zeolitic catalysts due to an intermolecular solvent effect in confined micropores

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Article information

DOI
https://doi.org/10.1039/C2CC32498A
Article type
Communication
Submitted
06 Apr 2012
Accepted
18 May 2012
First published
18 May 2012

Chem. Commun., 2012,48, 6936-6938

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Enhancement of Brønsted acidity in zeolitic catalysts due to an intermolecular solvent effect in confined micropores

A. Zheng, B. Han, B. Li, S. Liu and F. Deng, Chem. Commun., 2012, 48, 6936 DOI: 10.1039/C2CC32498A

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