Issue 57, 2012
From the journal:

Chemical Communications

A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere†

Hao Jiang,a   Lennart Lykke,a   Steen Uttrup Pedersen,a   Wen-Jing Xiaob  and  Karl Anker Jørgensen*a  

* Corresponding authors

a Dept. of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark
E-mail: kaj@chem.au.dk
Tel: +45 8942 3910

b Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Hubei 430079, Wuhan, China
E-mail: wxiao@mail.ccnu.edu.cn

Abstract

An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.

Graphical abstract: A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere

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Article information

DOI
https://doi.org/10.1039/C2CC32711B
Article type
Communication
Submitted
17 Apr 2012
Accepted
23 May 2012
First published
24 May 2012

Chem. Commun., 2012,48, 7203-7205

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A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere

H. Jiang, L. Lykke, S. Uttrup Pedersen, W. Xiao and K. Anker Jørgensen, Chem. Commun., 2012, 48, 7203 DOI: 10.1039/C2CC32711B

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