Issue 59, 2012
From the journal:

Chemical Communications

Oxozinc carboxylates: a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents†

Wojciech Bury,*a   Iwona Justyniak,b   Daniel Prochowicz,a   Zbigniew Wróbelb  and  Janusz Lewiński*ab  

* Corresponding authors

a Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
E-mail: lewin@ch.pw.edu.pl, wojbur@ch.pw.edu.pl
Web: http://lewin.ch.pw.edu.pl
Fax: (+)48-22-234-7279

b Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

Two unique adducts of an oxozinc carboxylate cluster with H2O and THF were isolated and structurally characterized, [Zn4(μ4-O)(O2CR)6(H2O)(THF)]·2(THF) and [Zn4(μ4-O)(O2CR′)6(THF)3] (where R = benzoate and R′ = 9-antracenecarboxylate anion). The study shows that the zinc centers of the Zn4O core can easily form unique coordination environments without breaking of the Zn–Ocarboxylate bonds.

Graphical abstract: Oxozinc carboxylates: a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents

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Article information

DOI
https://doi.org/10.1039/C2CC33094F
Article type
Communication
Submitted
29 Apr 2012
Accepted
30 May 2012
First published
31 May 2012

Chem. Commun., 2012,48, 7362-7364

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Oxozinc carboxylates: a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents

W. Bury, I. Justyniak, D. Prochowicz, Z. Wróbel and J. Lewiński, Chem. Commun., 2012, 48, 7362 DOI: 10.1039/C2CC33094F

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