Issue 68, 2012
From the journal:

Chemical Communications

Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition†

Robyn E. Fairbairn,a   Ross McLellan,a   Ruaraidh D. McIntosh,a   Stephanie M. Taylor,b   Euan K. Brechin*b  and  Scott J. Dalgarno*a  

* Corresponding authors

a Institute of Chemical Sciences, Heriot – Watt University, Riccarton, Edinburgh, Scotland, UK
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44 (0)131 451 3180
Tel: +44 (0)131 451 8025

b EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 7545

Abstract

Rare-earth octahedra have been previously synthesised using p-tert-butylcalix[4]arene as a cluster support. Introduction of a heteroatom bridge in the calixarene framework, with concomitant alteration to the nature of the metal binding pocket, influences lanthanide composition in the cluster.

Graphical abstract: Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition

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Article information

DOI
https://doi.org/10.1039/C2CC33166G
Article type
Communication
Submitted
02 May 2012
Accepted
03 Jul 2012
First published
04 Jul 2012

Chem. Commun., 2012,48, 8493-8495

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Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition

R. E. Fairbairn, R. McLellan, R. D. McIntosh, S. M. Taylor, E. K. Brechin and S. J. Dalgarno, Chem. Commun., 2012, 48, 8493 DOI: 10.1039/C2CC33166G

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