Issue 80, 2012
From the journal:

Chemical Communications

A simple nickel bis(dithiolene) complex as an excellent n-type molecular semiconductor for field-effect transistors†

Li Qu,a   Yunlong Guo,b   Hao Luo,b   Cheng Zhong,a   Gui Yu,b   Yunqi Liu*b  and  Jingui Qin*a  

* Corresponding authors

a Department of Chemistry and Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Wuhan University, Wuhan 430072, P. R. China
E-mail: jgqin@whu.edu.cn

b Beijing National Laboratory for Molecular Sciences and CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: liuyq@iccas.ac.cn

Abstract

A simple nickel bis(dithiolene) complex has been developed as an excellent n-type molecular semiconductor for FETs, with an electron mobility of 0.11 cm2 V−1 s−1 and an on/off ratio of 2 × 106 despite its small π-conjugated system. Good FET stability in ambient conditions has also been observed.

Graphical abstract: A simple nickel bis(dithiolene) complex as an excellent n-type molecular semiconductor for field-effect transistors

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Article information

DOI
https://doi.org/10.1039/C2CC33445C
Article type
Communication
Submitted
13 May 2012
Accepted
11 Jul 2012
First published
11 Jul 2012

Chem. Commun., 2012,48, 9965-9967

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A simple nickel bis(dithiolene) complex as an excellent n-type molecular semiconductor for field-effect transistors

L. Qu, Y. Guo, H. Luo, C. Zhong, G. Yu, Y. Liu and J. Qin, Chem. Commun., 2012, 48, 9965 DOI: 10.1039/C2CC33445C

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