Issue 63, 2012
From the journal:

Chemical Communications

Stereoselective intermolecular C–H amination reactions†

Hélène Lebel,*a   Carl Trudela  and  Cédric Spitza  

* Corresponding authors

a Département de chimie et Centre en chimie verte et catalyse (CCVC), Université de Montréal, 2900 Boul. Edouard Montpetit, Montréal, Québec, Canada
E-mail: helene.lebel@umontreal.ca
Tel: +1 514-343-5826

Abstract

A novel chiral N-mesyloxycarbamate to perform rhodium-catalyzed stereoselective C–H amination reactions is reported. Chiral benzylic and propargylic amines are produced in good yields and selectivities using ethyl acetate as solvent. The corresponding free amines are easily obtained by cleavage of the chiral reagent, which could also be recovered.

Graphical abstract: Stereoselective intermolecular C–H amination reactions

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Article information

DOI
https://doi.org/10.1039/C2CC33689H
Article type
Communication
Submitted
23 May 2012
Accepted
08 Jun 2012
First published
13 Jun 2012

Chem. Commun., 2012,48, 7799-7801

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Stereoselective intermolecular C–H amination reactions

H. Lebel, C. Trudel and C. Spitz, Chem. Commun., 2012, 48, 7799 DOI: 10.1039/C2CC33689H

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