Issue 76, 2012
From the journal:

Chemical Communications

Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction†

Leilei Wu,a   Volkan Degirmenci,a   Pieter C. M. M. Magusin,a   Bartłomiej M. Szyjaa  and  Emiel J. M. Hensen*a  

* Corresponding authors

a Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, Eindhoven, The Netherlands
E-mail: e.j.m.hensen@tue.nl
Fax: +31 40-245-5054
Tel: +31 40-247-5178

Abstract

The dual template synthesis of zeolite SSZ-13 by use of trimethyl-adamantanammonium hydroxide and a diquaternary-ammonium mesoporogen induces considerable mesoporosity without impeding zeolite microporosity. The strongly improved accessibility of Brønsted sites in mesoporous SSZ-13 increases its stability during application as an acid catalyst in the methanol-to-olefins reaction.

Graphical abstract: Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction

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Article information

DOI
https://doi.org/10.1039/C2CC33994C
Article type
Communication
Submitted
04 Jun 2012
Accepted
19 Jul 2012
First published
24 Jul 2012

Chem. Commun., 2012,48, 9492-9494

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Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction

L. Wu, V. Degirmenci, P. C. M. M. Magusin, B. M. Szyja and E. J. M. Hensen, Chem. Commun., 2012, 48, 9492 DOI: 10.1039/C2CC33994C

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