A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIV single-chain magnets

Indrani Bhowmick; Elizabeth A. Hillard; Pierre Dechambenoit; Claude Coulon; T. David Harris; Rodolphe Clérac

doi:10.1039/C2CC34066F

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A canted antiferromagnetic ordered phase of cyanido-bridged Mn^III₂Re^IV single-chain magnets†

Indrani Bhowmick,^ab Elizabeth A. Hillard,^ab Pierre Dechambenoit,^ab Claude Coulon,^ab T. David Harris^c and Rodolphe Clérac*^ab

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* Corresponding authors

^a CNRS, CRPP, UPR 8641, F-33600 Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr
Fax: +33 5 56 84 56 00
Tel: +33 5 56 84 56 50

^b Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

^c Department of Chemistry, University of California, Berkeley, CA, USA

Abstract

A new cyanido-bridged Re^IV–Mn^III heterometallic 1D system, [Mn^III(5-Me-saltmen)]₂[Re^IVCl₄(CN)₂]·3CH₃CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.

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Article information

DOI: https://doi.org/10.1039/C2CC34066F
Article type: Communication
Submitted: 06 Jun 2012
Accepted: 07 Aug 2012
First published: 09 Aug 2012

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Chem. Commun., 2012,48, 9717-9719

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A canted antiferromagnetic ordered phase of cyanido-bridged MnIII₂ReIV single-chain magnets

I. Bhowmick, E. A. Hillard, P. Dechambenoit, C. Coulon, T. D. Harris and R. Clérac, Chem. Commun., 2012, 48, 9717 DOI: 10.1039/C2CC34066F

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