Issue 69, 2012
From the journal:

Chemical Communications

Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative†

Sang Chul Lee,*a   Akira Ueda,*a   Hiromichi Kamo,a   Kazuyuki Takahashi,b   Mikio Uruichi,c   Kaoru Yamamoto,c   Kyuya Yakushi,c   Akiko Nakao,d   Reiji Kumai,e   Kensuke Kobayashi,e   Hironori Nakao,e   Youichi Murakamie  and  Hatsumi Mori*a  

* Corresponding authors

a The Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Japan
E-mail: hmori@issp.u-tokyo.ac.jp
Fax: +81-4-7136-3410
Tel: +81-4-7136-3410

b Department of Chemistry, Graduate School of Science, Kobe University, Kobe, Japan

c Institute for Molecular Science, Okazaki, Japan

d Research Center for Neutron Science and Technology, CROSS, Tokaimura, Japan

e Condensed Matter Research Center, Institute of Materials Structure Science, KEK, Tsukuba, Japan

Abstract

A unique N+–H⋯N hydrogen-bonded (H-bonded) dimer motif based on partially oxidized pyridyl-substituted TTF was constructed in the charge-transfer complex. The charge ordering in the TTF column by the charge disproportionation in the dimer regulates the arrangement of the H-bonded proton, evidencing the proton–electron coupled state.

Graphical abstract: Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

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Article information

DOI
https://doi.org/10.1039/C2CC34296K
Article type
Communication
Submitted
15 Jun 2012
Accepted
10 Jul 2012
First published
10 Jul 2012

Chem. Commun., 2012,48, 8673-8675

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Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

S. C. Lee, A. Ueda, H. Kamo, K. Takahashi, M. Uruichi, K. Yamamoto, K. Yakushi, A. Nakao, R. Kumai, K. Kobayashi, H. Nakao, Y. Murakami and H. Mori, Chem. Commun., 2012, 48, 8673 DOI: 10.1039/C2CC34296K

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