A versatile and highly enantioselective chiral Brønsted acid-catalyzed allenylation of aldehydes with propargyl borolane is reported. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, heteroaryl, α,β-unsaturated, and aliphatic aldehydes.
L. R. Reddy, Chem. Commun., 2012, 48, 9189 DOI: 10.1039/C2CC34371A
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