Issue 80, 2012
From the journal:

Chemical Communications

Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors†

Michael Giese,a   Markus Albrecht,*a   Tim Krappitz,a   Marius Peters,a   Verena Gossen,a   Gerhard Raabe,a   Arto Valkonenb  and  Kari Rissanenb  

* Corresponding authors

a Institut für Organische Chemie, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany
E-mail: markus.albrecht@oc.rwth-aachen.de
Fax: +49 241 809 2385
Tel: +49 241 809 4678

b Department of Chemistry, Nanoscience Center, University of Jyväskylä, Survontie 9, 40014 Jyväskylä, Finland
E-mail: kari.t.rissanen@jyu.fi
Fax: +358 14 260 2672
Tel: +358 50 562 3721

Abstract

A rare anion–π complex between bromide and a neutral receptor is reported and related receptor systems are studied with a series of anions. The interaction is observed in the solid state and in solution, and further evidence for it is obtained by a computational study.

Graphical abstract: Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors

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Article information

DOI
https://doi.org/10.1039/C2CC34748B
Article type
Communication
Submitted
03 Jul 2012
Accepted
23 Aug 2012
First published
04 Sep 2012

Chem. Commun., 2012,48, 9983-9985

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Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors

M. Giese, M. Albrecht, T. Krappitz, M. Peters, V. Gossen, G. Raabe, A. Valkonen and K. Rissanen, Chem. Commun., 2012, 48, 9983 DOI: 10.1039/C2CC34748B

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