Issue 77, 2012
From the journal:

Chemical Communications

Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties†

Jun Zhang,*a   Jun Fu,a   Xiaolong Su,a   Xinke Qin,a   Meixin Zhaoa  and  Min Shi*ab  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China
E-mail: zhangj@ecust.edu.cn
Tel: +86 021 64252995

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China
E-mail: mshi@mail.sioc.ac.cn
Tel: +86 021 64252995

Abstract

A series of new 2,3,5-triaryl-substituted oxazolium and thiazolium salts are readily prepared by a Tf2O-mediated intramolecular cyclisation and their use as precursors for the synthesis of novel oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes has been developed.

Graphical abstract: Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties

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Article information

DOI
https://doi.org/10.1039/C2CC35020C
Article type
Communication
Submitted
23 Jun 2012
Accepted
08 Aug 2012
First published
10 Aug 2012

Chem. Commun., 2012,48, 9625-9627

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Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties

J. Zhang, J. Fu, X. Su, X. Qin, M. Zhao and M. Shi, Chem. Commun., 2012, 48, 9625 DOI: 10.1039/C2CC35020C

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