Issue 87, 2012
From the journal:

Chemical Communications

Gold nanoparticles-catalyzed activation of 1,2-disilanes: hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcohols†

Charis Gryparisa  and  Manolis Stratakis*a  

* Corresponding authors

a Department of Chemistry, University of Crete, Voutes, 71003, Iraklion, Greece
E-mail: stratakis@chemistry.uoc.gr
Fax: +30 2810 545001
Tel: +30 2810 545087

Abstract

Gold nanoparticles supported on TiO2 catalyze under mild conditions the activation of a series of 1,2-disilanes towards hydrolysis and alcoholysis, with concomitant evolution of H2 gas. For the case of tert-benzyl alcohols, the main or only pathway is reduction to the corresponding alkanes.

Graphical abstract: Gold nanoparticles-catalyzed activation of 1,2-disilanes: hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcohols

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Article information

DOI
https://doi.org/10.1039/C2CC35116A
Article type
Communication
Submitted
17 Jul 2012
Accepted
12 Sep 2012
First published
13 Sep 2012

Chem. Commun., 2012,48, 10751-10753

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Gold nanoparticles-catalyzed activation of 1,2-disilanes: hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcohols

C. Gryparis and M. Stratakis, Chem. Commun., 2012, 48, 10751 DOI: 10.1039/C2CC35116A

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