Issue 92, 2012

The redox effect of the [1,2-(NH)2C6H4]2−ligand in the formation of transition metal compounds

Abstract

Reactions of the [1,2-(NH)2C6H4]2− dianion (LH22−) with Cp2MII (M = V, Mn) lead to complete or partial oxidation of the metals (M), giving the VIII compound [(η5-Cp)(LH2)2VV(LH2)][Li(THF)4]+ (1) and MnII4MnIII2 oxo cage [Mn6(LH2)66-O)(THF)4] (2).

Graphical abstract: The redox effect of the [1,2-(NH)2C6H4]2− ligand in the formation of transition metal compounds

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2012
Accepted
20 Aug 2012
First published
21 Aug 2012

Chem. Commun., 2012,48, 11298-11300

The redox effect of the [1,2-(NH)2C6H4]2− ligand in the formation of transition metal compounds

F. A. Stokes, L. Kloo, Y. Lv, P. J. Harford, A. E. H. Wheatley and D. S. Wright, Chem. Commun., 2012, 48, 11298 DOI: 10.1039/C2CC35213C

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