Issue 82, 2012
From the journal:

Chemical Communications

Bu4NI-catalyzed benzylic acyloxylation of alkylarenes with aromatic aldehydes†

Juan Huang,a   Lan-Tao Li,a   Hong-Ying Li,a   Ezizjan Husan,a   Peng Wanga  and  Bin Wang*a  

* Corresponding authors

a State Key Laboratory of Medicinal Chemical Biology, College of Pharmacy, Nankai University, 94 Weijin Road, Tianjin 300071, China
E-mail: wangbin@nankai.edu.cn
Fax: +86-22-23507760
Tel: +86-22-23506290

Abstract

An nBu4NI-catalyzed benzylic C–H acyloxylation of alkylarenes with readily available aromatic aldehydes has been developed. These reactions occur under mild and clean reaction conditions using tert-butyl hydroperoxide as the green terminal oxidant.

Graphical abstract: Bu4NI-catalyzed benzylic acyloxylation of alkylarenes with aromatic aldehydes

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Article information

DOI
https://doi.org/10.1039/C2CC35450K
Article type
Communication
Submitted
24 May 2012
Accepted
30 Aug 2012
First published
30 Aug 2012

Chem. Commun., 2012,48, 10204-10206

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Bu4NI-catalyzed benzylic acyloxylation of alkylarenes with aromatic aldehydes

J. Huang, L. Li, H. Li, E. Husan, P. Wang and B. Wang, Chem. Commun., 2012, 48, 10204 DOI: 10.1039/C2CC35450K

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