Issue 83, 2012
From the journal:

Chemical Communications

Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle†

Wissam Iali,a   Frédéric La Paglia,a   Xavier-Frédéric Le Goff,b   Dušan Sredojević,c   Michel Pfeffera  and  Jean-Pierre Djukic*a  

* Corresponding authors

a Institut de Chimie de Strasbourg, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, F-67000 Strasbourg, France
E-mail: djukic@unistra.fr
Fax: +33 (0)3 68 85 00 01
Tel: +33 (0)3 68 85 15 23

b Laboratoire “Hétéroéléments et Coordination”, Ecole Polytechnique, CNRS, F-91128 Palaiseau Cedex, France

c Faculty of Chemistry, University of Belgrade, Studentski trg, SRB-11000 Belgrade, Serbia

Abstract

A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild “one pot” conditions.

Graphical abstract: Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

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Article information

DOI
https://doi.org/10.1039/C2CC35520E
Article type
Communication
Submitted
30 Jul 2012
Accepted
30 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10310-10312

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Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

W. Iali, F. L. Paglia, X. L. Goff, D. Sredojević, M. Pfeffer and J. Djukic, Chem. Commun., 2012, 48, 10310 DOI: 10.1039/C2CC35520E

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