Issue 96, 2012
From the journal:

Chemical Communications

Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts†

Takato Mitsudome,a   Akifumi Noujima,a   Tomoo Mizugaki,a   Koichiro Jitsukawaa  and  Kiyotomi Kaneda*ab  

* Corresponding authors

a Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, Japan
E-mail: kaneda@cheng.es.osaka-u.ac.jp
Fax: +81 6-6850-6260
Tel: +81 6-6850-6260

b Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, Japan

Abstract

Hydrotalcite-supported gold nanoparticles (Au/HT) catalyzed the highly efficient double-carbonylation of amines to oxamides under mild reaction conditions. Various amines were selectively converted to the corresponding oxamides. The cooperation between gold nanoparticles and basic sites of HT plays a key role in the reaction.

Graphical abstract: Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts

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Article information

DOI
https://doi.org/10.1039/C2CC36636C
Article type
Communication
Submitted
12 Sep 2012
Accepted
08 Oct 2012
First published
08 Oct 2012

Chem. Commun., 2012,48, 11733-11735

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Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts

T. Mitsudome, A. Noujima, T. Mizugaki, K. Jitsukawa and K. Kaneda, Chem. Commun., 2012, 48, 11733 DOI: 10.1039/C2CC36636C

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