Issue 100, 2012
From the journal:

Chemical Communications

Tetrabutylammonium iodide catalyzed allylic sulfonylation of α-methyl styrene derivatives with sulfonylhydrazides†

Xiaoqing Li,*a   Xiangsheng Xua  and  Can Zhoua  

* Corresponding authors

a College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, P. R. China
E-mail: xqli@zjut.edu.cn
Fax: +86 571 88320799
Tel: +86 571 88320799

Abstract

Sulfonyl radicals generated from sulfonylhydrazides by the Bu4NI–tert-butyl hydroperoxide (TBHP) catalysis system underwent addition to a variety of α-methyl styrene derivatives to give the corresponding allylic sulfones. This selective allylic sulfonylation is metal-free, operationally simple, and environmentally friendly.

Graphical abstract: Tetrabutylammonium iodide catalyzed allylic sulfonylation of α-methyl styrene derivatives with sulfonylhydrazides

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Article information

DOI
https://doi.org/10.1039/C2CC36960E
Article type
Communication
Submitted
25 Sep 2012
Accepted
02 Nov 2012
First published
05 Nov 2012

Chem. Commun., 2012,48, 12240-12242

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Tetrabutylammonium iodide catalyzed allylic sulfonylation of α-methyl styrene derivatives with sulfonylhydrazides

X. Li, X. Xu and C. Zhou, Chem. Commun., 2012, 48, 12240 DOI: 10.1039/C2CC36960E

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