Issue 94, 2012
From the journal:

Chemical Communications

Hysteretic carbon dioxide sorption in a novel copper(ii)-indazole-carboxylate porous coordination polymer†

Chris S. Hawes,‡*a   Ravichandar Babarao,b   Matthew R. Hill,b   Keith F. White,c   Brendan F. Abrahamsc  and  Paul E. Kruger*a  

* Corresponding authors

a Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand
E-mail: paul.kruger@canterbury.ac.nz

b Commonwealth Scientific and Industrial Research Organisation, Private Bag 33, Clayton, Victoria 3169, Australia

c School of Chemistry, The University of Melbourne, Victoria 3010, Australia

Abstract

The synthesis, structural and gas sorption studies of a porous Cu(II) coordination polymer featuring 1H-indazole-5-carboxylic acid (H2L) are presented. [Cu(HL)2] is a thermally and hydrolytically robust 4-connected 3D coordination polymer of NbO topology and is replete with 1D channels that permit selective and hysteretic sorption of CO2.

Graphical abstract: Hysteretic carbon dioxide sorption in a novel copper(ii)-indazole-carboxylate porous coordination polymer

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Article information

DOI
https://doi.org/10.1039/C2CC37453F
Article type
Communication
Submitted
30 Jul 2012
Accepted
12 Oct 2012
First published
18 Oct 2012

Chem. Commun., 2012,48, 11558-11560

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Hysteretic carbon dioxide sorption in a novel copper(II)-indazole-carboxylate porous coordination polymer

C. S. Hawes, R. Babarao, M. R. Hill, K. F. White, B. F. Abrahams and P. E. Kruger, Chem. Commun., 2012, 48, 11558 DOI: 10.1039/C2CC37453F

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