Issue 2, 2012

Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]·CH2Cl2Electronic supplementary information (ESI) available: Additional data, Fig. S1 and S2, Tables S1–S3. CCDC reference number 805254. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce06322g

Abstract

The reaction of the deprotonated N-thiophosphorylated thiourea 6-MeO(O)CC6H4NHC(S)NHP(S)(OiPr)2 (HL) with NiCl2 leads to violet [NiL22]·CH22Cl22 crystals, which were isolated by recrystallization from a mixture of CH2Cl2 and n-hexane. It was established that the deprotonated ligands, L, are 1,5-S,S′-coordinated. The influence of CH2Cl2 for the complex stabilization was studied.

Graphical abstract: Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]·CH2Cl2

Supplementary files

Article information

Article type
Communication
Submitted
05 Oct 2011
Accepted
10 Nov 2011
First published
29 Nov 2011

CrystEngComm, 2012,14, 370-373

Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]·CH2Cl2

M. G. Babashkina, D. A. Safin, M. Srebro, P. Kubisiak, M. P. Mitoraj, M. Bolte and Y. Garcia, CrystEngComm, 2012, 14, 370 DOI: 10.1039/C1CE06322G

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