The polyprotic acid H3PO4 in a Li2SO4 supporting electrolyte has been effectively utilized as a catholyte donating three protons in dual-electrolyte Li–air cells. The cell offers a high capacity of 740 mA h g−1 at an average cell voltage of 3.3 V with good rechargeability and stability.
L. Li, X. Zhao, Y. Fu and A. Manthiram, Phys. Chem. Chem. Phys., 2012, 14, 12737 DOI: 10.1039/C2CP42250F
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