Issue 44, 2012
From the journal:

Physical Chemistry Chemical Physics

Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex†

Claudio Garino,*a   Erik Gallo,b   Nikolay Smolentsev,bc   Pieter Glatzel,b   Roberto Gobetto,a   Carlo Lamberti,a   Peter J. Sadlerd  and  Luca Salassa*de  

* Corresponding authors

a Department of Chemistry and NIS Centre of Excellence, University of Turin, Via P. Giuria 7, 10125 Turin, Italy
E-mail: claudio.garino@unito.it
Fax: +39 011 6707855
Tel: +39 011 6707946

b European Synchrotron Radiation Facility (ESRF), 6 Rue Jules Horowitz, 38043 Grenoble, France

c Research Center for Nanoscale Structure of Matter, Southern Federal University, Str. Sorge 5, 344090 Rostov-on-Don, Russia

d Department of Chemistry, University of Warwick, Gibbet Hill Rd, Coventry CV4 7AL, UK

e CIC biomaGUNE, Paseo Miramón 182, 20009 Donostia − San Sebastian, Spain
E-mail: lsalassa@cicbiomagune.es
Fax: +34 943 005301
Tel: +34 943 005309

Abstract

Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal–metal and π–π interactions on their energy.

Graphical abstract: Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

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Article information

DOI
https://doi.org/10.1039/C2CP42451G
Article type
Communication
Submitted
18 Jul 2012
Accepted
05 Sep 2012
First published
06 Sep 2012

Phys. Chem. Chem. Phys., 2012,14, 15278-15281

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Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

C. Garino, E. Gallo, N. Smolentsev, P. Glatzel, R. Gobetto, C. Lamberti, P. J. Sadler and L. Salassa, Phys. Chem. Chem. Phys., 2012, 14, 15278 DOI: 10.1039/C2CP42451G

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