Issue 46, 2012
From the journal:

Dalton Transactions

Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons†‡

Pavel A. Petrov,*ab   Dmitry Yu. Naumov,a   Rosa Llusar,*c   Carlos J. Gómez-García,d   Víctor Poloe  and  Sergey N. Konchenkoab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry SB RAS, Ak. Lavrentieva Av., 3, 630090 Novosibirsk, Russian Federation
E-mail: panah@niic.nsc.ru
Fax: +7 (383) 330 9489
Tel: +7 (383) 316 5831

b Novosibirsk State University, Pirogova St., 2, 630090 Novosibirsk, Russian Federation

c Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, Castelló, Spain
E-mail: Rosa.Llusar@qfa.uji.es
Fax: (+34) 964728066
Tel: (+34) 964728086

d Instituto de Ciencia Molecular (ICMol), Parque Científico, Universidad de Valencia, 46980 Paterna (Valencia), Spain

e Departamento de Química Física and Instituto de Biocomputación y Física de Sistemas Complejos (BIFI), Universidad de Zaragoza, 50009 Zaragoza, Spain

Abstract

The electron precise incomplete cuboidal complex [Mo3S4(dppe)3Br3]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo3S4(dppe)3(Br,Cl)3](Br,Cl) (1b) can be smoothly reduced to the paramagnetic [Mo3S4(dppe)3X3] clusters (2a, X = Br; 2b, X = Cl/Br) with 7 CSE by treatment with liquid Ga.

Graphical abstract: Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons

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Article information

DOI
https://doi.org/10.1039/C2DT31577G
Article type
Communication
Submitted
16 Jul 2012
Accepted
07 Aug 2012
First published
08 Aug 2012

Dalton Trans., 2012,41, 14031-14034

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Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons

P. A. Petrov, D. Yu. Naumov, R. Llusar, C. J. Gómez-García, V. Polo and S. N. Konchenko, Dalton Trans., 2012, 41, 14031 DOI: 10.1039/C2DT31577G

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