Issue 19, 2012
From the journal:

Organic & Biomolecular Chemistry

Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange†

Maiko Otsuka,a   Hiroya Yokoyama,a   Kohei Endob  and  Takanori Shibata*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, Japan
E-mail: tshibata@waseda.jp
Fax: +81-3-5286-8098
Tel: +81-3-5286-8098

b Waseda Institute for Advanced Study, Shinjuku, Tokyo, Japan

Abstract

A catalytic β-selective addition of amines to styrenes proceeded in the presence of cationic Ru complexes combined with diphosphine ligands. In the reaction of α-methylstyrene, an enantioselective addition was achieved by using xylylBINAP.

Graphical abstract: Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

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Article information

DOI
https://doi.org/10.1039/C2OB25457C
Article type
Communication
Submitted
01 Mar 2012
Accepted
23 Mar 2012
First published
27 Mar 2012

Org. Biomol. Chem., 2012,10, 3815-3818

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Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

M. Otsuka, H. Yokoyama, K. Endo and T. Shibata, Org. Biomol. Chem., 2012, 10, 3815 DOI: 10.1039/C2OB25457C

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