Issue 8, 2012
From the journal:

RSC Advances

Sterically congested pyrrole-fused tetrathiafulvalene decamers as highly conductive amorphous molecular materials†

Masayoshi Takase,*a   Naofumi Yoshida,a   Tomoyuki Narita,a   Takashi Fujio,a   Tohru Nishinagaa  and  Masahiko Iyoda*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo, Japan
E-mail: mtakase@tmu.ac.jp, iyoda@tmu.ac.jp

Abstract

Sterically congested pyrrole-fused tetrathiafulvalene (TTF) decamer 4 was designed and synthesized via the SNAr reaction of decafluorobiphenyl with the corresponding pyrrolyl sodium salt, which formed amorphous spin-coated films showing good conductivity of up to 4.4 S cm−1 after iodine doping as the result of multi-dimensional π–π stacking between the TTF units.

Graphical abstract: Sterically congested pyrrole-fused tetrathiafulvalene decamers as highly conductive amorphous molecular materials

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Article information

DOI
https://doi.org/10.1039/C2RA00035K
Article type
Communication
Submitted
05 Jan 2012
Accepted
14 Feb 2012
First published
07 Mar 2012

RSC Adv., 2012,2, 3221-3224

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Sterically congested pyrrole-fused tetrathiafulvalene decamers as highly conductive amorphous molecular materials

M. Takase, N. Yoshida, T. Narita, T. Fujio, T. Nishinaga and M. Iyoda, RSC Adv., 2012, 2, 3221 DOI: 10.1039/C2RA00035K

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