A novel method to reduce the influence of by-product water on the catalytic performance of PdCl2/Cu-HMS catalysts for the synthesis of diethyl carbonate

Pingbo Zhang; Mingming Fan; Pingping Jiang

doi:10.1039/C2RA20529G

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A novel method to reduce the influence of by-product water on the catalytic performance of PdCl₂/Cu-HMS catalysts for the synthesis of diethyl carbonate†

Pingbo Zhang,^a Mingming Fan*^a and Pingping Jiang^a

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* Corresponding authors

^a The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, PR China
E-mail: fanmm2000@126.com
Fax: +86-510-85917763
Tel: +86-510-85917090

Abstract

A novel method to synthesise diethyl carbonate is introduced by the coupling reaction, the hydrolysis of diethyl ether (DEE) and oxidative carbonylation of ethanol, which reduces the influence of by-product water and satisfies the energy coupling for the reaction system.

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Article information

DOI: https://doi.org/10.1039/C2RA20529G
Article type: Communication
Submitted: 22 Mar 2012
Accepted: 23 Mar 2012
First published: 23 Mar 2012

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RSC Adv., 2012,2, 4593-4595

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A novel method to reduce the influence of by-product water on the catalytic performance of PdCl₂/Cu-HMS catalysts for the synthesis of diethyl carbonate

P. Zhang, M. Fan and P. Jiang, RSC Adv., 2012, 2, 4593 DOI: 10.1039/C2RA20529G

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