A catalytic enantioselective electrocyclic cascade leads to the construction of topologically complex systems comprising multiple rings with up to three stereocentres. This phase-transfer catalysed process offers a new strategy for the rapid and enantioselective generation of complex products bearing all-carbon quaternary stereogenic centres.
E. E. Maciver, P. C. Knipe, A. P. Cridland, A. L. Thompson and M. D. Smith, Chem. Sci., 2012, 3, 537 DOI: 10.1039/C1SC00697E
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