Issue 9, 2012
From the journal:

Chemical Science

Gold meets enamine catalysis in the enantioselective α-allylic alkylation of aldehydes with alcohols†

Michel Chiarucci,a   Marzia di Lillo,a   Alessandro Romaniello,a   Pier Giorgio Cozzi,a   Gianpiero Ceraa  and  Marco Bandini*a  

* Corresponding authors

a Department of Chemistry, “G. Ciamician”, Alma Mater Studiorum-University of Bologna, via Selmi 2, 40126, Bologna, Italy
E-mail: marco.bandini@unibo.it
Fax: +39-051 2099456
Tel: +39-051 2099751

Abstract

Synergetic gold(I)- and organo-catalysis proved to be efficient towards the intramolecular stereoselective α-allylic alkylation of aldehydes with simple primary and secondary alcohols. High diastereo- and enantioselectivity were recorded.

Graphical abstract: Gold meets enamine catalysis in the enantioselective α-allylic alkylation of aldehydes with alcohols

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2SC20478A
Article type
Edge Article
Submitted
18 Apr 2012
Accepted
26 Jun 2012
First published
27 Jun 2012

Chem. Sci., 2012,3, 2859-2863

Permissions

Request permissions

Gold meets enamine catalysis in the enantioselective α-allylic alkylation of aldehydes with alcohols

M. Chiarucci, M. di Lillo, A. Romaniello, P. G. Cozzi, G. Cera and M. Bandini, Chem. Sci., 2012, 3, 2859 DOI: 10.1039/C2SC20478A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements