Enhancing selectivity in stripping voltammetry by different adsorption behaviors: the use of nanostructured Mg–Al-layered double hydroxides to detect Cd(ii)

Abstract

We report the use of nanostructured layered double hydroxides (LDHs) for the highly selective and sensitive detection of Cd²⁺ using anodic stripping voltammetry (ASV). In particular, the modification of a glassy carbon electrode promotes the sensitivity and selectivity towards Cd²⁺ in the presence of Pb²⁺, Hg²⁺, Cu²⁺ and Zn²⁺. The electrochemical characterization and anodic stripping voltammetric performance of Cd²⁺ were evaluated using cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV) analysis. Operational parameters, including supporting electrolytes, pH value, deposition potential and deposition time were optimized. In addition, the selectivity, interference and stability were also investigated under the optimized conditions. The results showed that the fabricated electrode possessed good selectivity, stability and reproducibility. The proposed electrochemical sensing strategy is thus expected to open new opportunities to broaden the use of ASV in analysis for detecting heavy metal ions in the environment.