Issue 39, 2013

Observation of face-to-face host–guest associated states prior to threading of dialkylammonium ions into the DB24C8-like openings of a molecular cage

Abstract

The threading of bis(dialkylammonium) ions through the DB24C8-like openings of a molecular cage proceeds through a stepwise mechanism: formation of a face-to-face complex between the NH2+ centers and the crown ether, significant dissociation of this complex, and passage of the terminus of the cation through the macrocycle.

Graphical abstract: Observation of face-to-face host–guest associated states prior to threading of dialkylammonium ions into the DB24C8-like openings of a molecular cage

Supplementary files

Article information

Article type
Communication
Submitted
29 Jun 2012
Accepted
31 Aug 2012
First published
17 Sep 2012

Chem. Commun., 2013,49, 4199-4201

Observation of face-to-face host–guest associated states prior to threading of dialkylammonium ions into the DB24C8-like openings of a molecular cage

C. Chuang, M. Yen, C. Lai, Y. Liu, S. Peng and S. Chiu, Chem. Commun., 2013, 49, 4199 DOI: 10.1039/C2CC34669A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements