A tris(phosphino)amide-ligated Zr–Co heterobimetallic complex has been shown to activate N–H bonds of hydrazine derivatives via a proton-coupled electron transfer process. Such reactivity is highly unusual for an early metal such as Zr, but is promoted by the adjacent redox active Co atom.
J. W. Napoline, M. W. Bezpalko, B. M. Foxman and C. M. Thomas, Chem. Commun., 2013, 49, 4388 DOI: 10.1039/C2CC35594A
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