Issue 1, 2013
From the journal:

Chemical Communications

Nickel-catalyzed decyanation of inert carbon–cyano bonds†

Tuhin Patra,a   Soumitra Agasti,a   Akankshaa  and  Debabrata Maiti*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India
E-mail: dmaiti@chem.iitb.ac.in

Abstract

Nickel catalyzed decyanation of aryl and aliphatic cyanides with hydrosilane as the hydride source has been developed. This method is easy to handle, scalable and can be carried out without a glove box. The method has been applied in the cyanide directed functionalization reaction and α-substitution of benzyl cyanide.

Graphical abstract: Nickel-catalyzed decyanation of inert carbon–cyano bonds

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Article information

DOI
https://doi.org/10.1039/C2CC36883H
Article type
Communication
Submitted
22 Sep 2012
Accepted
06 Nov 2012
First published
06 Nov 2012

Chem. Commun., 2013,49, 69-71

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Nickel-catalyzed decyanation of inert carbon–cyano bonds

T. Patra, S. Agasti, Akanksha and D. Maiti, Chem. Commun., 2013, 49, 69 DOI: 10.1039/C2CC36883H

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