Issue 31, 2013
From the journal:

Chemical Communications

Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand†

Christian Torborg,a   Grzegorz Szczepaniak,a   Adam Zieliński,a   Maura Malińska,a   Krzysztof Woźniaka  and  Karol Grela*a  

* Corresponding authors

a University of Warsaw, Faculty of Chemistry, Pasteura 1, 02-093 Warsaw, Poland
E-mail: klgrela@gmail.com

Abstract

Stable and active Ru olefin metathesis catalyst 7 bearing a sterically reduced NHC ligand was synthesized. Upon action of pyridine, 7 forms complex 24, the first example of an Ru–indenylidene catalyst bearing a labile pyridine ligand and a sterically less demanding NHC ligand.

Graphical abstract: Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand

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Article information

DOI
https://doi.org/10.1039/C2CC37514A
Article type
Communication
Submitted
15 Oct 2012
Accepted
06 Dec 2012
First published
04 Jan 2013

Chem. Commun., 2013,49, 3188-3190

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Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand

C. Torborg, G. Szczepaniak, A. Zieliński, M. Malińska, K. Woźniak and K. Grela, Chem. Commun., 2013, 49, 3188 DOI: 10.1039/C2CC37514A

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