Issue 39, 2013
From the journal:

Chemical Communications

Donor–acceptor cyclopropanes with Lawesson's and Woollins' reagents: formation of bisthiophenes and unprecedented cage-like molecules†‡

Johannes Kaschel,a   Christian D. Schmidt,a   Mark Mumby,a   Daniel Kratzert,b   Dietmar Stalkeb  and  Daniel B. Werz*a  

* Corresponding authors

a Institut für Organische und Biomolekulare Chemie der Georg-August-Universität Göttingen, Tammannstr. 2, D-37077 Göttingen, Germany
E-mail: dwerz@gwdg.de
Fax: +49 (551)399476
Tel: +49 (551)393251

b Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstr. 4, D-37077 Göttingen, Germany

Abstract

Furan-derived donor–acceptor-substituted cyclopropanes were reacted with Lawesson's reagent. Depending on the reaction conditions either bisthiophenes or unprecedented cage-like molecules were obtained. Woollins' reagent always led to the respective selenium-containing cage-like compounds.

Graphical abstract: Donor–acceptor cyclopropanes with Lawesson's and Woollins' reagents: formation of bisthiophenes and unprecedented cage-like molecules

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Article information

DOI
https://doi.org/10.1039/C2CC37631H
Article type
Communication
Submitted
19 Oct 2012
Accepted
06 Dec 2012
First published
07 Dec 2012

Chem. Commun., 2013,49, 4403-4405

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Donor–acceptor cyclopropanes with Lawesson's and Woollins' reagents: formation of bisthiophenes and unprecedented cage-like molecules

J. Kaschel, C. D. Schmidt, M. Mumby, D. Kratzert, D. Stalke and D. B. Werz, Chem. Commun., 2013, 49, 4403 DOI: 10.1039/C2CC37631H

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