Issue 11, 2013

Activation of dichloromethane by a V(iii) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

Abstract

A VIII thiolate complex activated C–Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

Graphical abstract: Activation of dichloromethane by a V(iii) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

Supplementary files

Article information

Article type
Communication
Submitted
27 Oct 2012
Accepted
17 Dec 2012
First published
17 Dec 2012

Chem. Commun., 2013,49, 1109-1111

Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

T. Chen, Y. Chen, Y. Chang, J. Wang, Y. Tsai, G. Lee, T. Kuo and H. Hsu, Chem. Commun., 2013, 49, 1109 DOI: 10.1039/C2CC37801A

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