Issue 14, 2013
From the journal:

Chemical Communications

Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand†

Haiying Gana  and  Bruce C. Gibb*b  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, USA

b Department of Chemistry, Tulane University, New Orleans, USA
E-mail: bgibb@tulane.edu

Abstract

Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400–1500 Å3 and 3200–3700 Å3 respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.

Graphical abstract: Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand

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Article information

DOI
https://doi.org/10.1039/C2CC38227J
Article type
Communication
Submitted
14 Nov 2012
Accepted
21 Dec 2012
First published
02 Jan 2013

Chem. Commun., 2013,49, 1395-1397

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Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand

H. Gan and B. C. Gibb, Chem. Commun., 2013, 49, 1395 DOI: 10.1039/C2CC38227J

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