Issue 38, 2013
From the journal:

Chemical Communications

Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals†

Kyung Hwan Park,a   Tae Hwan Noh,a   Yoon-Bo Shima  and  Ok-Sang Jung*a  

* Corresponding authors

a Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Pusan 609-735, Korea
E-mail: oksjung@pusan.ac.kr
Fax: +82 51 516 7421
Tel: +82 51 510 2591

Abstract

Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.

Graphical abstract: Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

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Article information

DOI
https://doi.org/10.1039/C3CC00005B
Article type
Communication
Submitted
01 Jan 2013
Accepted
25 Mar 2013
First published
25 Mar 2013

Chem. Commun., 2013,49, 4000-4002

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Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

K. H. Park, T. H. Noh, Y. Shim and O. Jung, Chem. Commun., 2013, 49, 4000 DOI: 10.1039/C3CC00005B

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