Issue 27, 2013
From the journal:

Chemical Communications

A “pillar-free”, highly porous metalloporphyrinic framework exhibiting eclipsed porphyrin arrays†

Jacob A. Johnson,a   Qipu Lin,a   Lai-Chin Wu,bc   Nasrat Obaidi,a   Zachary L. Olson,a   Tyler C. Reeson,a   Yu-Sheng Chenb  and  Jian Zhang*a  

* Corresponding authors

a Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588, USA
E-mail: jzhang3@unl.edu

b ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 S. Cass Avenue, Argonne, IL 60439, USA

c Center for Materials Crystallography, Department of Chemistry and iNANO, Aarhus University, DK-8000 Aarhus, Denmark

Abstract

A “pillar-free”, highly porous metalloporphyrinic framework (UNLPF-1) exhibiting eclipsed porphyrin arrays has been constructed from an octacarboxylate ligand connected with paddlewheel secondary building units. UNLPF-1 possesses two types of open metal sites and exhibits an efficient selectivity toward capture of CO2 over N2.

Graphical abstract: A “pillar-free”, highly porous metalloporphyrinic framework exhibiting eclipsed porphyrin arrays

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Article information

DOI
https://doi.org/10.1039/C3CC00049D
Article type
Communication
Submitted
03 Jan 2013
Accepted
17 Feb 2013
First published
19 Feb 2013

Chem. Commun., 2013,49, 2828-2830

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A “pillar-free”, highly porous metalloporphyrinic framework exhibiting eclipsed porphyrin arrays

J. A. Johnson, Q. Lin, L. Wu, N. Obaidi, Z. L. Olson, T. C. Reeson, Y. Chen and J. Zhang, Chem. Commun., 2013, 49, 2828 DOI: 10.1039/C3CC00049D

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