Issue 21, 2013
From the journal:

Chemical Communications

Spin-active metallofullerene stabilized by the core of an NC moiety†

Yongqiang Feng,a   Taishan Wang,*a   Jingyi Wu,b   Yihan Ma,a   Zhuxia Zhang,a   Li Jiang,a   Chunhua Ge,*c   Chunying Shua  and  Chunru Wang*a  

* Corresponding authors

a Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: wangtais@iccas.ac.cn, crwang@iccas.ac.cn
Tel: +86-10-62652120

b Laboratory of Nuclear Analysis Techniques, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, China

c College of Chemistry, Liaoning University, Shenyang, China
E-mail: chhge@lnu.edu.cn
Tel: +86-24-62202550

Abstract

A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

Graphical abstract: Spin-active metallofullerene stabilized by the core of an NC moiety

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Article information

DOI
https://doi.org/10.1039/C3CC38445D
Article type
Communication
Submitted
23 Nov 2012
Accepted
30 Jan 2013
First published
30 Jan 2013

Chem. Commun., 2013,49, 2148-2150

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Spin-active metallofullerene stabilized by the core of an NC moiety

Y. Feng, T. Wang, J. Wu, Y. Ma, Z. Zhang, L. Jiang, C. Ge, C. Shu and C. Wang, Chem. Commun., 2013, 49, 2148 DOI: 10.1039/C3CC38445D

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